9/1/2023 0 Comments Entropy equation![]() The ionic solid is highly ordered, and so has a relatively low entropy. What happens when an ionic solid dissolves in water? There are more ways of arranging the energy of the molecule in a disordered way over bigger molecules than smaller ones. This is because benzene is a more complicated molecule. Notice that the benzene values are bigger than those of water-steam. That's because the hydrogen bonding between the liquid molecules imposes a fair amount of order on them even in the liquid. Notice that there isn't very big jump in entropy when ice turns to water. The entropy increases as the molecules become more disordered as you go from solid to liquid to gas. What happens during change of state? The following figures are for the standard entropy of water in different states. ![]() These all have low entropies because they are highly ordered solids, but notice that the entropy usually increases as the solid gets more complicated. Here are some standard entropies for a few solids, all with the units J K -1mol -1: carbon (as diamond) Use whatever units the examiners give you. 1 bar is 100 kPa 1 atmosphere is 101.325 kPa. Don't worry about it - they are nearly the same. You might find the pressure quoted as 1 atmosphere rather than 1 bar in older sources. This includes solid to liquid, liquid to gas and solid to aqueous solution.Įntropy is given the symbol S, and standard entropy (measured at 298 K and a pressure of 1 bar) is given the symbol S°. If you look in textbooks or on the web, you will find explanations of increasing difficulty - some very scary indeed! Don't waste time on these at this level. "a system becomes more stable when its energy is spread out in a more disordered state". The entropy has increased in terms of the more random distribution of the energy. The faster moving particles have more energy the slower ones less. After a very short time, their arrangement in space will be chaotic, and so will the way energy is shared between them. And then you let them go and do what molecules do - move around, and bump into each other and the walls of the container.Įach collision between two molecules will cause them to change direction, and it will probably speed up one of them, and slow down the other. Suppose you managed to arrange some gaseous molecules in a container so that they were all exactly evenly spaced and so that they all had exactly the same energy - a fairly ordered state. A system which is more disordered in space will tend to have more disorder in the way the energy is arranged as well. But we often just quickly look at how disordered a system is in space in order to make a judgement about its entropy. Technically, entropy applies to disorder in energy terms - not just to disordered arrangements in space. Now, it is just imaginable that when you dropped them, by chance they would fall into a neat stack of coins like the one you started with, but the probability of that happening, compared to all the other ways that the coins might fall, is so very, very tiny that you would be totally amazed if it happened. Every time you did this, you would get a different random pattern of coins on the floor - arranged just by chance. That's a fairly ordered state for them to be in. ![]() Suppose you held a stack of ten coins between your finger and thumb. We now expand on this a bit, but luckily not too much! Let's look at this with a couple of thought experiments. ![]() A very disordered system (a mixture of gases at a high temperature, for example) will have a high entropy. A very regular, highly ordered system (diamond, for example) will have a very low entropy. This page provides a simple, non-mathematical introduction to entropy suitable for students meeting the topic for the first time.Īt this level, in the past, we have usually just described entropy as a measure of the amount of disorder in a system. ![]()
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![]() ![]() Morlacchi - The Swiss Shepherd (a bit dorky of theme, but folk like it!) Grade 6-7 standard flute repertoire: gypsy-style/Hungarian/ethnic folk-theme flute musicĭonjon - Eight Salon Etudes - especially those like "Les Follets" which is terrific for this style of music and so very attractive to students. (Click on the grade 5&6 video below hear a performance Andersen's Intermezzo at 1:45 minute mark.)Īmirov - Six Pieces the three movements selected here are PERFECT for students who want to sound rough, rollicking, folksy and middle-European! :>)Īnd of course, for grade six and higher I can also suggest the standard repertoire: Grade 6 Overtones: Andersen Intermezzo opus 52 no. Grade 5 Overtones book: Check out the Szervanszky Sonatina Now: Continuing up the grade levels to flute grades 5 and 6: I have chosen those flute pieces that are either in minor/moody modes, have fun and boppy sixteenth note passages, have a strong emotional appeal to teens, or have a folk music style themes. (with lovely photos randomly added from the cameras of my friends and I). įor these short videos, below, I've chosen all the similar style selections from the Grade 4 Overtones book, made fade-out clips so you can hear for yourself. Hear Tanzlied using the grade 4 repertoire video below from Overtones CD. Grade 4 Overtones: Andersen Tanzlied opus 52, bk.2 Here are my flute repertoire picks for an exact match: The five biggest winners for an exact match in style to the Hungarian Serenade by Joncieres are these selections from the new Overtones Flute Repertoire series: ( note: I am not related to the sales of any flute books for any company in any way-I just love these graded flute solo collections! See indexes at bottom of this post.**) Of course it's tricky to know from your email exactly what difficulty level you need without hearing the students, but I'll start with suggestions for grade 4-7 so you can have an idea about the levels I'm using ( a chart of flute levels is here.) So many students go through that "gypsy wanderer and flashy gypsy dance" stage, that I've always felt we should have more repertoire choices for them. I wish there were more!įortunately, there is a great deal of a similar style of music in the new Overtones flute series of repertoire books.Īs I read through this set of eight repertoire books (with flute & piano full parts plus playalong CDs each book is only $18 to $24 each grade) I was struck by how many are in attractively exotic sounding minor keys, are nice and moody/emotional, have the kind of flash and flair and fast staccato sixteenth notes that highschool students typically love. Yes Hungarian style Serenades and other "gypsy-esque" pieces are so popular with teens between 12 and 16. I have found your website to be wonderful and fascinating. Their interest and abilities are admittedly somewhat limited of course. ![]() They would love to play more pieces like this one, but I’m having trouble finding anything appropriate. Specifically, I have a couple of students who have been excited by and excelled at playing the “Hungarian Serenade” by Joncieres (in the Cavally, 24 Short concert Pieces book). I’m a flutist and teacher and just read your blog about the Xmas trios and thought I would ask your advice about repertoire for intermediate level HS students. ![]() 9/1/2023 0 Comments Wizard with a gun destiny![]() ![]() You now know everything there is to know about enemies in Destiny 2. Simply put, Powerful enemies are Major and Ultra enemies, including Elites, Minibosses, Champions, Bosses, and vehicles. Jul 2 5:14pm Cannot play the demo anymore like it says purchase but the game hasnt released yet < > Showing 1-15 of 18.![]() Wizard with a Gun > General Discussions > Topic Details. Some quests and bounties will ask you to defeat Powerful enemies. All Discussions Screenshots Artwork Broadcasts Videos News Guides Reviews. These are affected by the Minor spec and are often referred to as ads. Rank and File enemies are Minor enemies that have a red health bar. What are rank and file enemies in Destiny 2? This section is meant to cover some of the biggest questions we see online. And to make matters worse, their naming is deeply flawed, with different terms sometimes having the exact same meaning. It has to be said that the enemy classification in Destiny 2 is overly complicated. I am back and Ive dug up a whole of load of new details on Wizard with a Gun We discuss the bullets, armour and gameplay. Now you can see what it does Players can use the First Edition to scan objects in world and learn about them. There are currently 6 different enemy factions in Destiny 2: So, we told you what the First Edition is. This is the complete list of Enemies in Destiny 2, including their Elemental shields and damage:. We cover them in depth in our Champions guide, including how to beat them. There are 3 different types of Champions in Destiny 2: These are some of the most challenging enemies in the entire game, especially because they require very precise mods to be defeated. It can also be farmed from the SMG rabbit at the end of the Chaos Chambers.Shadowkeep added a new type of enemy to Destiny 2: Champions. The Wizard’s Pipe is also a World Drop, so it can randomly drop from any source. Parasite has the infamous triple health bar, so make sure to bring a Lightning, Frost, and Fire weapon. You will want to use the Fast Travel called What’s Left of Driftwood as it will drop you right in front of the arena. The Wizard heads back to the 1920s in this Roaring 21 Casino Review. He can be found in Tangledrift, more specifically in the area known as Driftwood. and Promotions The List No deposit bonus. ![]() You can farm this Legendary SMG from the boss named Parasite. Where to find the Wizard’s Pipe in Tiny Tina’s Wonderlands Wizard with a Gun - Wizard with a Gun is an online cooperative sandbox survival game set in a magical wilderness wrought with dangerous creatures and arcane mysteries. For instance, if you are fighting a Bone enemy, the Wizard’s Pipe will send out Frost orbs. Way of the West Wheels of Destiny note Cyclone of the Saddle The Drunkard Five. The fashion show has begun A sub dedicated to the many looks of Destiny, a. The special ability of this Legendary is that it occasionally shoots out homing orbs with the damage type that’s most effective against the enemy they are tracking. 1933 King Kong Gibson, George 1939 The Wizard of Oz. It also gets better accuracy the longer you fire the gun. Time To Die This barren earth defiled by man Raped & tortured, yeah whatever man Hatred, greed & misery Is this to be, our foul destiny I wanna scream but. Hell, heat metal an opposing riflemans gun for a fatal disarm. Molding earth as they push a position, or casting fireball without the need for a grenade. When you aim down sights you receive a front-facing shield that can absorb incoming damage. Honestly, the concept of a wizard with a gun is terrifying. Embark on a journey alone or with a friend to collect, craft, and outfit your wizard however you see fit as you explore the unknown. The Wizard’s Pipe is a Hyperius SMG that can drop in all elements. Wizard with a Gun - Wizard with a Gun is an online cooperative sandbox survival game set in a magical wilderness wrought with dangerous creatures and arcane mysteries. ![]() 9/1/2023 0 Comments Teletext holidays reviews 2015![]() ![]() The air costs are only a fraction of the costs of the holiday. The excuse that you are awaiting refund from the airline is rubbish!!. You are dishonesty and unethically holding on to my hard earned money for no good reason. You need to call me as soon as this is viewed to resolve this issue. You have my contact details on your system and my booking reference. I will call every day until I get my refund. When I call I'm being constantly fobbed off, they just don't give a damn.Įvery day I am kept waiting I will leave an accurate and honest but reputation damaging review on every site I can find, until I get a refund. ![]() This company is earning thousands of pounds in interest holding on to the millions they owe. They will not answer any of my emails or live chats. When they finally answer I have had the phone call hung up on me twice on the two calls. This is causing me financial hardship and the money is needed.Įvery time I call I'm kept waiting for between 45 and 90 minutes. ![]() I am being told I will have to wait until the end of September for my refund. I paid almost £4000 for my holiday which was cancelled by them in early June. THIS COMPANY IS DISHONEST AND MORALLY CORRUPT!!! This is going to be the first on many reviews I'll be leaving until I get a refund!!!!!!! ![]() 9/1/2023 0 Comments Boondock rv![]() Boondocking sites tend to be first come, first served, and do not require reservations.ĭry camping is often confused with boondocking. Some boondocking sites may charge a small overnight fee, but this is typically less than $20 per night. Most often, boondocking is free, which makes it a great way for campers to save money and experience unspoiled nature. Air conditioners and furnaces require too much power to temperature control an RV during extreme heat or cold, making it difficult to boondock in many areas throughout the year. Photo: Alyssa Padgettīecause your RV isn’t hooked up to electricity, boondocking is popular during months and in areas where temperatures aren’t extreme, like the mountains of Colorado in the summer and the deserts of Arizona in the winter. ![]() Boondocking in this way is sometimes referred to as wild, primitive, or dispersed camping and often comes with Instagram-worthy views. Most of the time when campers talk about boondocking, they’re referring to camping in national forests or on BLM (Bureau of Land Management) land. You can boondock in many different ways, like staying overnight in a business parking lot or camping on public lands. ![]() In this article:īoondocking in an RV is when you camp without hookups to electricity, water, or sewage. But knowing the basics of boondocking can be useful for any camper-it’s cheap, convenient, and gives you access to incredible views you otherwise might not see. ![]() While some campers enjoy the outdoors at traditional RV parks with full hookups and free WiFi, others opt to rough it with boondocking. For many campers, RVing is about being outside, relaxing in nature, and finding peace in the beauty of the outdoors. ![]() 8/31/2023 0 Comments La guerra civil dazn release date![]() ![]() ![]() We already work with some of the biggest names and organisations in sport and film today, but as DAZN continues to grow, we also want to enable the next generation of filmmakers and invest in the future talent of sports storytelling. "We know that the way we tell stories never stops evolving. "DAZN Studios is going to enable us to broaden our original programming offering with productions that not only drive deeper engagement with fans but create opportunities via licensing, distribution, advertising and commissions. “Sport has the power to inspire and connect people around the world, and evocative storytelling can bring us closer to its beating heart," said DAZN Chief Operating Officer, Ed McCarthy, in January. The sneak peek of La Guerra comes at the start of DAZN's month-long celebrations of Hispanic Heritage Month, which will see exclusive interviews, classic content and more become available to subscribers over the next four weeks, with additional HHM content being made available to all fight fans via DAZN's official YouTube channel. and Oscar De La Hoya, will be available to subscribers of the DAZN sports streaming platform in the very near future after a fresh hint was dropped on social media. La Guerra Civil is part of DAZN Studios' 2022 slate of several original documentaries looking back at the legends of sport and their respective rises to prominence.Īlso announced by the company back in January were Ronnie, a biopic about legendary former Brazil striker Ronaldo, Green Lions, a look back at Cameroon's incredible journey at the 1990 World Cup, and Maradona: The Fall, an explosive look behind the scenes of the Argentine icon's failed drug test and subsequent fallout at the 1994 World Cup in the United States. La Guerra Civil, a documentary looking back at the historic boxing rivalry between Hispanic fight icons Julio Cesar Chavez Snr. IfK26Bq2xm- DAZN Boxing September 16, 2022 The ultimate battle for Mexican pride □□ ![]() 8/31/2023 0 Comments Blender software![]() ![]() Programs released under this license can be used at no cost for both personal and commercial purposes. Open Source software is software with source code that anyone can inspect, modify or enhance. Freeware products can be used free of charge for both personal and professional (commercial use). Also Available: Blender (32-bit), Blender for Mac and Blender Portableįreeware programs can be downloaded used free of charge and without any time limitations. 3D: 3D Studio (3DS), COLLADA (DAE), Filmbox (FBX), Autodesk (DXF), Wavefront (OBJ), DirectX (x), Lightwave (LWO), Motion Capture (BVH), SVG, Stanford PLY, STL, VRML, VRML97, X3D. Video: AVI, MPEG, and Quicktime (on OSX). Image: JPEG, JPEG2000, PNG, TARGA, OpenEXR, DPX, Cineon, Radiance HDR, SGI Iris, TIFF. ![]() File Formats The app comes packed with import/export support for many different programs. From simply splitting their viewport, to fully customizing it with python scripting, the tool works for you. Flexible Interface Novice and advanced users will love the ability to customize their layout completely. Library of Extensions With a large community of enthusiasts and developers, the program comes loaded with a vast array of extensions that you can turn on or off easily. Eliminating the need to switch between programs. Allowing you to import raw footage, track the footage, mask areas, and see the camera movements live in your 3d scene. Camera and Object tracking The software now includes a production-ready camera and object tracking. Game Creation Included in the app is a complete game engine, allowing you to create a fully-featured 3d game right inside the app. Amazing Simulations Whether you need a crumbling building, rain, fire, smoke, fluid, cloth, or full-on destruction, the app delivers great-looking results. That means no more exporting to third party programs, you can do it all without leaving the program. ![]() Full Compositor The software comes with a fully-fledged compositor built right in. Fast UV Unwrapping Easily unwrap your mesh right inside the app, and use image textures or paint your own directly onto the model. ![]() Sculpting Experience the joy of sculpting organic subjects using the built-in sculpting feature set of the program. Fast Rigging Transforming a model into a poseable character has never been easier! Animation toolset Whether it’s simple keyframing or complex walk-cycles, the tool allows artists to turn their still characters into impressive animations. Realistic Materials With the product’s new rendering engine the possibilities for materials are endless. Fast Modelling The app’s comprehensive array of modeling tools make creating, transforming, and editing your models a breeze. Features and Highlights Photorealistic Rendering The tool now features a powerful new unbiased rendering engine called Cycles that offers stunning ultra-realistic rendering. Blender has no price tag, but you can invest, participate, and help to advance a powerful collaborative tool: The software is your own 3D software. Its interface uses OpenGL to provide a consistent experience. Blender 64-bit is cross-platform and runs equally well on Linux, Windows, and Macintosh computers. The app is well suited to individuals and small studios who benefit from its unified pipeline and responsive development process. Advanced users employ the tool’s API for Python scripting to customize the application and write specialized tools often these are included in Blender’s future releases. It supports the entirety of the 3D pipeline-modeling, rigging, animation, simulation, rendering, compositing and motion tracking, even video editing and game creation. Blender 64-bit is a free and open-source 3D animation suite software. ![]() 8/31/2023 0 Comments Dave ramsey financial freedom![]() Money: Master The Game by Tony Robbins Favorite Quote ![]() If you want to learn more, you can read our free four-minute summary or get a copy for yourself.Ģ.
8/31/2023 0 Comments Speed up boot time windows 10![]() ![]() There is GPT header and partition table redundancy as they are located in the beginning and ending LBAs of a drive. It can boot off of partitions that are greater than 2.2TB in size. It is backwards compatible with MBR as it leaves an MBR in LBA 0. Like UEFI, the GPT is a bit more advanced and has some benefits to it. The MBR allows for you to create partitions on a storage medium and allows a BIOS or UEFI to see the active partition to boot off of it. GPT and MBR are different partitioning schemes that set the partitioning layout of a storage medium. On the software side of things you also need support, the system drive needs to have a GUID Partition Table or GPT when the OS is installed onto it, not the standard Master Boot Record or MBR we are used to and older BIOS’s understand. Also, one thing to note is that the Ultra Fast mode will boot so fast that you may have to use a UEFI setup utility from your motherboard manufacturer to enter back into the UEFI once it is enabled. We will talk about what cards are compatible later on. ![]() Now what the heck does UEFI GOP compliant even mean? It basically means that your graphics card supports native UEFI Ultra Fast booting. The Ultra Fast option allows the motherboard UEFI to initialize all the hardware at once vs sequentially as with a BIOS, thus speeding up the POST process, however, you have to have a UEFI GOP (Graphics Output Protocol) compliant graphics card. Ultra Fast is where things might seem to get a bit complicated, but really they aren’t. Fast means that it will cut some of the checks during POST to speed up the POST process. Disabled means that it will do a normal boot with no speeding up of the POST. Typically there are three options, Disable, Fast, and Ultra Fast (also called hardware boot, Windows feature, or something similar in the UEFI). The latest UEFI motherboards have fast boot options integrated in them under the boot tab menu. Without getting to deep into details, UEFI has a lot of benefits over the old BIOS firmware we are used to, including the ability to use the mouse, more security, and much faster POST and boot capabilities. If you have a computer that was built within the last 3-4 years, chances are that it has a different firmware called a Unified Extensible Firmware Interface or UEFI implementation. Over the past few years firmware has been progressing quite a bit. It also allows the OS a way to interact with the system’s I/O. ![]() It handles initialization and testing the system hardware as well as loading a boot loader or operating system. You are probably familiar with this term and have gone into a BIOS to tweak settings for your system, whether it be to change the boot order or overclock your system. On older systems, the motherboard’s firmware is called a Basic Input/Output System or BIOS. PCs have specialized software called firmware that controls the hardware. Today, we are going to go over how to optimize your system and do a native UEFI Windows installation to speed up your boot time as fast as possible! When we say ultra-fast, we mean powered off system to desktop in 6-10 seconds.ĭoes this sound crazy? Well, it really isn’t. There are some other things you can do than just slapping an SSD in your system and setting the SATA mode to AHCI or RAID to achieve ultra-fast boot times by using the latest hardware. SSDs will sometimes cut minutes off boot times when compared to hard drives, however, more often than not, many people do not know how to properly configure, or even know that it is possible to configure their system in such a way to speed up their boot time even more. As you know, many people buy SSDs to not only speed up their computing experience, but also speed up the boot time of their machines. ![]() 8/31/2023 0 Comments Iphone shortcuts automation![]()
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